Volume 9, Issue 4 (2018)
JMBS 2018, 9(4): 603-609 |
Back to browse issues page
Download citation:
BibTeX | RIS | EndNote | Medlars | ProCite | Reference Manager | RefWorks
Send citation to:
BibTeX | RIS | EndNote | Medlars | ProCite | Reference Manager | RefWorks
Send citation to:
Khoshkbar Sadeghi A, Farbodi M. Preparation of Polyaniline/Polyvinyl Alcohol/Ag Nanocomposite and Characterization of Its Physicochemical and Antibacterial Properties. JMBS 2018; 9 (4) :603-609
URL: http://biot.modares.ac.ir/article-22-13538-en.html
URL: http://biot.modares.ac.ir/article-22-13538-en.html
1- Chemistry Department, Tabriz Branch, Islamic Azad University, Tabriz, Iran
2- Chemistry Department, East Azarbayjan Science & Research Branch, Islamic Azad University, Tabriz, Iran, Chemistry Department, East Azarbayjan Science & Research Branch, Islamic Azad University, Tabriz, Iran ,m.farbodi@iaut.ac.ir
2- Chemistry Department, East Azarbayjan Science & Research Branch, Islamic Azad University, Tabriz, Iran, Chemistry Department, East Azarbayjan Science & Research Branch, Islamic Azad University, Tabriz, Iran ,
Abstract: (4617 Views)
Aims: The simultaneous use of insulating polymers and nanostructures such as silver to produce triangular nanocomposites, with the reinforcement of effect of each other, can have better results in improving the mechanical properties and processability of polyaniline. The current study was conducted with the aim of preparation of Polyaniline/Polyvinyl Alcohol/Ag nanocomposite and characterization of its physicochemical and antibacterial properties.
Materials and Methods: In the present experimental research, polyaniline (PANI) was used as a conducting polymer, polyvinyl alcohol (PVA) was used as a biopolymer because of its biodegradable property. Ag nanoparticles also was considered as a reinforcing agent of thermal stability, mechanical and antibacterial property to prepare PANI-PVA-Ag nanocomposite.
The synthesis of PANI-PVA composite and PANI-PVA-Ag nanocomposite was performed through polyaniline and Ag addition in PVA solution. Different weight percent of components and Fourier-Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), Thermogravimetric Analysis (TGA), and scanning electron microscope connected to the X-ray Diffraction System (EDX) were used to investigate the properties.
Findings: Thermal stability of the nanocomposite in comparison with pure PVA in temperatures above 400ᵒC was promoted. The presence of PANI, PVA, and Ag in the FTIR spectroscopy showed the compatibility of the nanocomposite components. The greatest tensile strength belonged to PANI/PVA/Ag nanocomposites with 88%, 9%, and 3%w/w.
Conclusion: The components of Polyaniline/Polyvinyl Alcohol/Ag are compatible. The presence of PANI and Ag nanoparticles in the structure of the nanocomposite improves its thermal stability than pure PVA at high temperatures. Polyaniline/Polyvinyl Alcohol/Ag canocomposite has inhibitory effect on gram-positive and gram-negative pathogenic bacteria. Reducing the weight percent of PVA or increasing the weight percent of PANI decrease the tensile strength.
Materials and Methods: In the present experimental research, polyaniline (PANI) was used as a conducting polymer, polyvinyl alcohol (PVA) was used as a biopolymer because of its biodegradable property. Ag nanoparticles also was considered as a reinforcing agent of thermal stability, mechanical and antibacterial property to prepare PANI-PVA-Ag nanocomposite.
The synthesis of PANI-PVA composite and PANI-PVA-Ag nanocomposite was performed through polyaniline and Ag addition in PVA solution. Different weight percent of components and Fourier-Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), Thermogravimetric Analysis (TGA), and scanning electron microscope connected to the X-ray Diffraction System (EDX) were used to investigate the properties.
Findings: Thermal stability of the nanocomposite in comparison with pure PVA in temperatures above 400ᵒC was promoted. The presence of PANI, PVA, and Ag in the FTIR spectroscopy showed the compatibility of the nanocomposite components. The greatest tensile strength belonged to PANI/PVA/Ag nanocomposites with 88%, 9%, and 3%w/w.
Conclusion: The components of Polyaniline/Polyvinyl Alcohol/Ag are compatible. The presence of PANI and Ag nanoparticles in the structure of the nanocomposite improves its thermal stability than pure PVA at high temperatures. Polyaniline/Polyvinyl Alcohol/Ag canocomposite has inhibitory effect on gram-positive and gram-negative pathogenic bacteria. Reducing the weight percent of PVA or increasing the weight percent of PANI decrease the tensile strength.
Article Type: _ |
Subject:
Agricultural Biotechnology
Received: 2017/08/27 | Accepted: 2017/11/11 | Published: 2018/12/21
Received: 2017/08/27 | Accepted: 2017/11/11 | Published: 2018/12/21
References
1. Araujo JR, Adamo CB, Costa e Silva MV, De Paoli MA. Antistatic-reinforced biocomposites of polyamide-6 and polyaniline-coated curauá fibers prepared on a pilot plant scale. Polym Compos. 2013;34(7):1081-90. [Link] [DOI:10.1002/pc.22516]
2. Shabani Nooshabadi M, Ghoreishi SM, Behpour M. Electropolymerized polyaniline coating on aluminum alloy 3004 and their corrosion protection performance. Electrochimica Acta. 2009;54(27):6989-95. [Link] [DOI:10.1016/j.electacta.2009.07.017]
3. Tsotra P, Friedrich K. Thermal, mechanical, and electrical properties of epoxy resin/polyaniline-dodecylbenzenesulfonic acid blends. Synth Met. 2004;143(2):237-42. [Link] [DOI:10.1016/j.synthmet.2003.12.016]
4. Mirmohseni A, Oladegaragoze A, Farbodi M. Synthesis and characterization of processable conducting polyaniline/polystyrene composite. Iran Polym J. 2008;17(2):135-40. [Link]
5. Afzal AB, Javad Akhtar M, Nadeem M, Hassan MM. Dielectric and impedance studies of DBSA doped polyaniline/PVC composites. Curr Appl Phys. 2010;10(2):601-6. [Link] [DOI:10.1016/j.cap.2009.08.004]
6. Ghaffari Moghaddam M, Eslahi H. Synthesis, characterization and antibacterial properties of a novel nanocomposite based on polyaniline/polyvinyl alcohol/Ag. Arab J Chem. 2014;7(5):846-55. [Link] [DOI:10.1016/j.arabjc.2013.11.011]
7. Yavuz AG, Uygun A, Bhethanabotla VR. Substituted polyaniline/chitosan composites: Synthesis and characterization. Carbohydr Polym. 2009;75(3):448-53. [Link] [DOI:10.1016/j.carbpol.2008.08.005]
8. Liu H, Liu BH, Li ZP. A reduced graphene oxide/SnO2/polyaniline nanocomposite for the anode material of Li-ion batteries. Solid State Ion. 2016;294:6-14. [Link] [DOI:10.1016/j.ssi.2016.06.008]
9. Nguyen VH, Shim JJ. Green synthesis and characterization of carbon nanotubes/polyaniline nanocomposites. J Spectrosc. 2015;2015:297804. [Link]
10. Wang L, Lu X, Lei S, Song Y. Graphene-based polyaniline nanocomposites: Preparation, properties and applications. J Mater Chem A. 2014;2(13):4491-509. [Link] [DOI:10.1039/C3TA13462H]
11. Saadat L, Sadeghvandi F. Synthesis & study of Polyethylene/Polyaniline/Montmorillonite ductile nano composites properties. Int J Nano Dimens. 2014;5(3):255-65. [Link]
12. Gupta K, Jana PC, Meikap AK. Optical and electrical transport properties of polyaniline-silver nanocomposite. Synth Met. 2010;160(13-14):1566-73. [Link] [DOI:10.1016/j.synthmet.2010.05.026]
13. Olad A, Nosrati R. Preparation and corrosion resistance of nanostructured PVC/ZnO-polyaniline hybrid coating. Prog Org Coat. 2013;76(1):113-8. [Link] [DOI:10.1016/j.porgcoat.2012.08.017]
14. Olad A, Barati M, Behboudi S. Preparation of PANI/epoxy/Zn nanocomposite using Zn nanoparticles and epoxy resin as additives and investigation of its corrosion protection behavior on iron. Prog Org Coat. 2012;74(1):221-7. [Link] [DOI:10.1016/j.porgcoat.2011.12.012]
15. Singho ND, Che Lah NA, Johan MR, Ahmad R. FTIR studies on silver-poly (Methylmethacvylate) nanocomposites via In-situ polymerization technigue. Int J Electrochem Sci. 2012;7(6):5596-603. [Link]
16. Dos Reis EF, Campos FS, Lage AP, Leite RC, Heneine LG, Vasconcelos WL, et al. Synthesis and characterization of poly (vinyl alcohol) hydrogels and hybrids for rMPB70 protein adsorption. Mater Res. 2006;9(2):185-91. [Link] [DOI:10.1590/S1516-14392006000200014]
17. Alimohammadi F, Montazer M, Shamei A, Rahimi MK. Synthesis of silver nanoparticles in cotton fabric by polyvinyl-2-pyrrolidone as a reducing and stabilizing agent. Iran J Polym Sci Technol. 2012;25(4):265-75. [Persian] [Link]
Send email to the article author
| Rights and permissions | |
 |
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License. |